"Percent" means "per hundred". 25% is 25 out of every 100, which is the same as the fraction 25/100 or the decimal 0.25.
To turn a percent into a decimal, divide by 100. In practice that means moving the decimal point two places to the left:
Every percent problem involves three numbers: a part, a whole and a percent. If you know two of them, you can always find the third.